Extraction-spectrophotometric determination of cobalt(II) with 2-hydroxy-1-naphthaldoxime

Solid phase extraction and spectrophotometric determination of Au(III) with 5-(2-hydroxy-5-nitrophenylazo)thiorhodanine.

A new chromogenic reagent, 5-(2-hydroxy-5-nitrophenylazo)thiorhodanine (HNATR) was synthesized. A highly sensitive, selective and rapid method for the determination microg l(-1) level of Au(III) based on the rapid reaction of Au(III) with HNATR and the solid phase extraction of the colored complex with a reversed phase polymer-based C(18) cartridge have been developed. The HNATR reacted with Au...

Extraction and Spectrophotometric Determination of Copper (Ii) with 1-(2-Metoxiphenylamin)-3-Metoksipropanthiol-2

The alloys of copper find extensive use in automobile radiators, heat exchangers, home heating systems and panels for absorbing solar energy. Copper (II) is a biologically active metal; its compounds affect the vital activity of plant and animal organisms. Copper is one of essential elements required for normal human metabolism [1]. Copper (II) is known to play a significant role in biological ...

Extraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide

A sensitive and selective extraction - spectrophotometric method for the determination of trace amounts of palladium is reported. The method is based on quantitative extraction of brownish tetrabutylammoium tetraiodopalladium (II) ion pair into a small valume of chloroform at pH 1.3-12.0, followed by spectrophotometric measurements. The Beer's law is obeyed over the range 0.02-1.09 <em...

Spectrophotometric Determination of 4-Hydroxy-2-mercapto-6-methylpyrimidine Based on Aggregation of Colloidal Gold Nanoparticles

We report herein the development of a highly sensitive colorimetric method for the detection of 4-hydroxy-2-mercapto-6-methylpyrimidine (MTU) which acts as an anti-thyroid drug utilizing citrate capped gold nanoparticles (Au-NPs). This thiol-containing molecule exhibits intriguing affinity with Au-NPs. The reactivity involves the displacement of the citrate shell by the thiolate shell followed ...

Selective extraction spectrophotometric determination